Thanks xLow!
You can choose whatever zener voltage value you want. I chose 5.6v cuz it actually measures out at 6v when you add the 0.4v of the control pin to it. It's simply a safety voltage value to shut the converter off when the input voltage drops to 6v.
There are 2 zeners - one for the converter and one for the LED - one to shut the converter off when the input voltage drops to 6v and the zener in line with the LED acts as a battery status indicator that prevents the LED from lighting when the voltage drops to 6v - letting you know it's time to charge the batts. The LED will light brightly when the batts are fully or nearly fully charged then dims as the input voltage drops, then is off when the input voltage is 6v or less.
The 220 ohm resistor is in line with the LED to limit the current
through the LED.