There is nothing wrong with your proposal, the issues associated with multiple cells are all to do with charging.
To charge a 7.4v battery, you need more than 7.4V and alongside that, the cells have to be charged to equal voltages (or else they have a nasty habit of going pop). If you run them in parallel, you'll need to make sure again, that both cells charge equally. In general this is beyond the capabilities of most simple charging circuits, but obviously chargers for this configuration do exist.
There isn't much benefit to converting a 2S cell into a 1S higher mAh cell. And RC lipos have very low internal resistance making it a good power source for high power
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